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Globally, irrigated agriculture is the largest extractor and the most frequent consumer of groundwater resources, with important groundwater-dependent and largely spread agro-economies. Quality of irrigation water is one of the key factors which have either direct or indirect impact on plant growth, soil and water management practices and plant yields. This work aims at highlighting the importance of periodic assessment of groundwater quality for irrigation, impact of different chemical parameters on plant yield and agriculture and water management practices needed in adverse irrigation water conditions. This study was conducted in semi-arid area where salinity and alkalinity are considered the main threats to the sustainable irrigation agriculture. Thirty representative samples were collected for chemical analyses from various sources of groundwater, within an area of 36 km2, lying in the north-east of the Lakki Marwat district Pakistan. The standard values suggested by WAPDA, FAO and USDA Handbook 60 were used as benchmark for comparison. The electrical conductivity and pH values together classify groundwater as saline-alkaline. It is revealed that none of the water samples has an adverse impact on the yield of barley, sorghum and wheat while 7% and 17% of this water respectively reduce the yield of corn and onion by 50%. Besides, 7% of this water reduces the yield of alfalfa by 25%. This work recommends management practices such as deep ploughing, provision of adequate drainage and crop rotation for improving the use of such water.

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Manufacturing industries synthesize new chemical products every day, which eventually find their ways into domestic and industrial wastewaters. As a result, wastewater is becoming increasingly more complex in nature. The emerging pollutants escape the treatment systems and appear in the receiving water bodies. Wastewater treatment plants in India still report effluent parameters in terms of BOD and COD at ppm level, whereas these emerging pollutants, many of whom are non-biodegradable, can be toxic and carcinogenic at ppb level. Therefore, it is imperative to look for alternatives or upgrade the existing systems which safely remove these harmful compounds from wastewater. In this research, efficiency of electrocoagulation process was assessed in a laboratory-scale setup in removing recalcitrant carbon from a real wastewater. The wastewater was collected from an effluent treatment plant that receives domestic wastewater and industrial effluents from chemical, bulk drugs and allied industries, for treatment. In this study the wastewater sample was analysed for total dissolved solids (TDS) and total organic carbon (TOC), and then treated biologically in a respirometer using aerobic microorganisms. After the oxygen uptake curve plateaued, indicating a cessation of biological process, the sample was analysed for TDS and TOC and put in a lab-scale electrocoagulation setup. Iron and Aluminium electrodes were used in the study and efficiency of the system in removing the recalcitrant / residual carbon and TDS was studied with respect to the reaction time. The results showed that electrocoagulation can be a potential post-biological treatment system for removal of recalcitrant carbon from wastewaters.